2007年4月23日 星期一

Group IV(AL8)

講完晒 phy chem同 org chem後,到係時候同同學仔講 inorg chem。Inorg chem係e個syllabus改咗唔少,取消咗nitrogen 同埋sulphur兩個topics。但亦加入GroupIV e個topic。Group IV最特別係同一個group裡面嘅elements有好唔同properties。其實e o個topic都係舊瓶新酒,佢o向兩代前嘅syllabus都有o架啦。

e個topic有3個重點:


1. Interpretation of variation in melting point and boiling point of the elements in terms of structure and bonding (e個group由carbon係non-metal 到 silicon and germanium 係 semi-metals 到最後tin and lead 係metals)

經典pastpaper: 1993 Paper II 4b

2. decomposition of group IV oxides and chlorides (同學仔要知道group IV嘅compounds有兩個possible 嘅oxidation states +4同 +2;+4 嘅oxidation states stability decrease down the group; 而+2 oxidation state 嘅stability increase down the group; 佢嘅原因可以用inert pair effect 去解釋)

經典pastpaper: 1992 paper II 5b同埋1994 paper II 6

3. silicon and silicates,e part係全新內容,冇pastpaper。但係化學友發現教統局製作咗一份reference material可以幫助同學仔溫習,你地可以去e個網址睇吓:

http://cd1.emb.hkedcity.net/cd/science/chemistry/s67chem/chem.htm (click L&T activities然後o向other learning activities就會搵到Silicates 硅酸鹽嘅notes )

重點係留意silicate嘅不同嘅basic units。

1 則留言:

hahayi2007 提到...

你之前有題mechanism 有無答案?
是不是HONO2 的OH的O打落去H2SO4個H到,甩左水,因為H2SO4係more acidic than HONO2
跟住NO2+再比double bond of benzene attack,跟住就照做落去..
我想問下..atom economy如果有隻reactant 係in excess,咁係計formula mass of reactant定係mass of reactant?
thx.